General and Inorganic Chemistry (2013/2014)



Course code
4S00136
Credits
9
Coordinator
Adolfo Speghini
Academic sector
CHIM/03 - GENERAL AND INORGANIC CHEMISTRY
Language of instruction
Italian
Teaching is organised as follows:
Activity Credits Period Academic staff Timetable
teoria 6 I semestre Adolfo Speghini
laboratorio [laboratorio I] 2 I semestre Adolfo Speghini
laboratorio [laboratorio II] 2 I semestre Adolfo Speghini
esercitazioni 1 I semestre Adolfo Speghini

Lesson timetable

I semestre
Activity Day Time Type Place Note
teoria Monday 8:30 AM - 12:30 PM lesson Lecture Hall Berni (Lebrecht)  
teoria Wednesday 8:30 AM - 12:30 PM lesson Lecture Hall Berni (Lebrecht)  
laboratorio [laboratorio I] Monday 1:30 PM - 5:30 PM laboratorio Lecture Hall Berni (Lebrecht)  
laboratorio [laboratorio I] Wednesday 1:30 PM - 5:30 PM laboratorio Lecture Hall Berni (Lebrecht)  

Learning outcomes

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Module: Theory
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The course provides the fundamental concepts of General Chemistry and some basics of Inorganic Chemistry. In particular:
- models and general concepts as means of justification and prediction of physical and chemical properties of systems of increasing degree of complexity: atoms, molecules, substances, multi-component systems (homogeneous and heterogeneous).
- concepts and methods for predicting qualitative and quantitative changes of intensive and extensive properties of chemical systems in transformation.

Module: Laboratory
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Numerical exercises integrate the knowledge acquired by the student in the theoretical part of the Course, in order to to teach the student how to solve problems of chemical interest.
The experiments in the General Chemistry laboratory integrate the knowledge acquired by the student in the theoretical part of the Course. The student learns how to manage problems of chemical interest, obtains information about the common equipment present in a chemical laboratory and how to work in safe conditions.

Syllabus

Module: Theory
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Introduction. Chemical and physical properties of matter and their measurements.
Elements, atoms and compounds.
Nomenclature of inorganic compounds.
Types of chemical reactions. Reaction stoichiometry.
Ideal and real gases.
Thermochemistry. Internal energy and enthalpy. Standard enthalpy of reaction and formation.
Atomic structure. Atomic orbitals. Electronic configuration, Aufbau principle.
Periodic properties: atomic and ionic radii, ionization energy, electron affinity, electronegativity.
Elementary notions on the ionic bond. Ionic compounds.
Covalent bond. Lewis formula. Resonance. Molecular geometry and polarity. Orbital hybridisation. Single and multiple bonds.
Interparticle forces.
Properties of liquids. Solutions. Colligative properties. Binary liquid mixtures. Distillation.
Properties of solids.
Chemical kinetics. Arrhenius equation. Reaction mechanisms.
Chemical equilibrium. Equilibrium constant.
Acid-base equilibrium. Acid, base and salt solutions. Acid-base titration. Buffer solutions.
Solubility equilibrium.
Entropy. Spontaneous processes. Gibbs free energy. Standard free energy of reaction and formation.
Electrochemical cells. Electrolysis.

Module: Laboratory
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Stoichiometry problems solving.


Laboratory experiments:
- determination of the hydrogen peroxide concentration in commercial samples for pharmaceutical use
- determination of the number of water molecules in hydrate copper sulphate
- spectrophotometric determination of the concentration of a potassium permanganate solution
- weak base-strong acid titration
- strong base-strong acid titration
- determination of drinking water hardness

Assessment methods and criteria

The final examination consists of a written part, consisting of stoichiometry problems and general questions and of an oral part.

Reference books
Activity Author Title Publisher Year ISBN Note
teoria Petrucci, Herring, Madura, Bissonnette Chimica Generale - Principi ed Applicazioni Moderne - con esercizi (Edizione 11) Piccin Nuova Libraria, Padova 2018 978-88-299-2933-7
teoria Martin S. Silberberg CHIMICA - La natura molecolare della materia e delle sue trasformazioni (Edizione 3) McGraw-Hill Education, Italy 2016 978-88-386-1542-9
esercitazioni Maurizio Bruschi Stechiometria e Laboratorio di Chimica Generale Pearson Italia, Milano, Torino 2011 978-88-7192-576-9